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Contents

 

 


Plenary Lectures [1-5]

1. Computerized Prediction of Thermodynamic Properties and Intelligent Data Base for Phase

  Diagrams of Molten Salt Systems.....................................................................................................

........................... Chen Nianyi, Yan Licheng, Lu Wencong, Bao Xinhua, Fang Jianhui, Ding Yimin  (1)

2. Nanoscale Electrodeposition from Molten Salts.............................................. Werner Freyland  (9)

3. On the Electrocatalysis of the Carbon Anode in Aluminium Electrolysis.............................................

................................................... Liu Yexiang, Lai Yanqing, Yang Jianhong and Jomar Thonstad  (16)

4. Vibrational Spectra and Structure of Molten Metal Fluorides................. G. N. Papatheodorou  (28)

5. Technology of Molten Salts Electrolysis to Produce Lanthanoid Metals and Alloys for Magnet

  Application on Industrial Manufacturing Basis...................................................................................

.............................. Hideo Tamamura, Mituo Aoyagi, Saburo Wakamatsu and Kazunori Ichioka  (36)

 


6. Refined Ionic Models for Lanthanide and Actinide Halides............. Z. Akdeniz and M. P. Tosi  (44)

7. A Model for the Anomalous Electronic Properties of Liquid Silver Chalcogenides.............................

.......................................................................................................................... Masaru Aniya   (49)

8. Some Regularities of Formation of Continuous Solid Solutions from Molten Halide Melt

  Mixtures........................... Bao Xinhua, Chen Nianyi, Lu Wencong, Fang Jianhui, Ding Yiming  (53)

9. Structures of Solid Salt Eutectics Using the Raman Microscope........................................................

......................................................................................... Rolf W. Berg and David H. Kerridge  (57)

10. Influence of PbO Content on the Properties of Some Oxide Glasses That Reproduce

   Industrial Wastes...........................................................................................................................

................ C. Bessada, M. Constantinescu, E. M. Anghel, M. Malki, P. Echegut and M. Olteanu  (61)

11. Nuclear Magnetic Resonance Studies of the Na2B4O7-Na3AlF6-TiO2 System.................................

......................................................................................................... C. Bessada, E. M. Anghel  (65)

12. Oxidation of Methane in Oleum at Elevated Temperatures..............................................................

................................................................................................. Niels J. Bjerrum and Xiao Gang  (69)

13. The Microstructure Study of Nickel Flash Smelting Slag.................................................................

........................................................ Cao Zhanmin, Klaus W. Richter, Xing Xianran, Qiao Zhiyu  (75)

14. Novel Cathodic Processes in Molten Salts...................... George Z. Chen and Derek J. Fray  (79)

15. Structure and Properties of the LiF–NaF–K2NbF7 Melts................................................................

......................................................... M. Chrenková, V. Danielik, V. Van, P. Fellner, V. Daněk  (86)

16. Effect of Anode Quality on Composition of Gases in Aluminium Electrolysis....................................

............................................................................ V. Daněk, A. Silný, M. Chrenková, Z. Pánek  (94)

17. Physicochemical Properties of Inorganic Powder Molten Carbonates Coexisting Systems II............

............................................................................ Shigehito Deki, Minoru Mizuhata, Yasuyuki Harada,

.................................................................................. Hajime Watanabe and Akihiko Kajinami  (101)

18. Doped α-Fe2O3---New Cathode Materials for MCFC...............................................................

....................... Ding Yimin, Yan Licheng, Fang Jianhui, Chen Nianyi, Cao Guangyi, Zhu Xinjian  (107)

19. Phase Diagram of LiCl-NiCl2 Molten Salts System.........................................................................

................................................................... Fang Jianhui, Shen Xia, Yan Licheng, Chen Nianyi  (110)

20. The Contents of Alkali and Earth Alkaline Metals in the Aluminium Cathode in Aluminium

   Electrolysis............................................... P. Fellner, V. Danielik, J Híveš, and J. Thonstad  (114)

21. Al-Coated Graphite Electrode as Negative Electrode Material for Secondary Lithium-Ion

   Battery Application in the Room Temperature Molten Salts....... …………………………………..

…………………………………………………………………..Y. S. Fung and D. R. Zhu  (118)

22. Electrical Conductance of Molten MCl – SmCl3 Mixtures (M = Li, Na, Rb, Cs).............................

............................................................................... M. Gaune-Escard, L. Rycerz, A. Potapov  (122)

23. Formation of III-V Nitrides by Molten Salt Electrochemical Process...............................................

................................................................................................ Takuya Goto and Yasuhiko Ito  (126)

24. Destruction of Organic Wastes Using Molten Carbonates...............................................................

.............................. Trevor R. Griffiths, Stephen Barr, Vladimir A. Volkovich, Elena M. Anghel  (130)

25. A Highly Conductive RTMS; Alkylimidazolium Fluorohydrogenates........................ Rika Hagiwara,

.......... Lazuhiko Matsumoto, Tetsuya, Tsuda, Shinji Kohara, Kentaro Suzuya and Yasuhiko Ito  (136)

26. Corrosion in Metal Halide Lamps...................................................................................................

.......................................... K. Hilpert, T. Karwath, T. Markus, U. Niemann, and L. Singheiser  (140)

27. Raman Spectroscopic Study of Solid and Molten Carbonates.........................................................

.................... Hou Huaiyu, You Jinglin, Jiang Guochang, Wu Yongquan, Chen Hui, Xu Kuangdi  (146)

28. Some Nonconventional Electrochemical Reactions in Molten Chloride Systems...............................

........................................................................................................................... Yasuhiko Ito  (150)

29. Precipitation of Bismuth and Bismuth Sulfide in Borate Glasses........................................................

.................................................... H. Itoigawa, T. Kamiyama, J. Kawamura and Y. Nakamura  (156)

30. Structural Analysis of Hydrous Sodium Carboxylate Melt by High-Energy X-Ray Diffraction

   Measurement.......................................... Akihiko Kajinami, Heisuke Nishikawa, Tsuyoshi Kotake,

........................................ Shigehito Deki, Ichiro Sakai, Shinji Kohara, and Norimasa Umesaki  (160)

31. Electrochemical Synthesis of Chromogenic Rare Earth Doped Vanadium Oxide Films.....................

.................................................................................................................. Yoshikazu Kaneko  (164)

32. Electrochemical Synthesis of Refractory Borides and Carbon Nano-Micro Tubes from

   Molten Salts......... G. Kaptay, I. Sytchev, M. S. Yaghmaee, Á. Kovács, E. Cserta, M. Árk  (168)

33. Estimation of Thermodynamic Properties of Pure Liquid Titanium Dichloride...................................

....................................................................................................................... George Kaptay  (174)

34. Coating Quartz Samples by Metallic Titanium in Molten Salts..........................................................

..................................................................................... G. Kaptay, I. Sytchev, Zs. H. Göndör  (178)

35. On the Surface Tension of Pure Molten Alkali Halides................................ George Kaptay  (182)

36. Electrodeposition and Anodic Dissolution of Tungsten in ZnCl2-NaCl Melts....................................

.............................................................................................................................. A. Katagiri  (186)

37. Electrochemical Behavior of Ferrocene in Some Hydrophobic Room Temperature Molten

   Salt Systems...................................................................... Yasushi Katayama, Makoto Yukumoto,

............................................................... Masaki Yamagata, Takashi Miura, and Tomiya Kishi  (190)

38. Physicochemical Diagnostics and Structure of Molten Salt Electrolytes............................................

............................................................................................................. Vladimir A. Khokhlov  (194)

39. Corrosion of Metallic Materials in Molten Alkaline Halogenides and Carbonates.............................

......................................................................... V. Ya. Kudyakov, S. M. Perin, A. E. Domnin  (200)

40. Determination of Ohmic Voltage Drop and Factors Influencing Anodic Overvoltage of

   Carbon Anodes in Cyrolite-Alumina Melts.....................................................................................

................................................ Yanqing Lai, Qingyu Li, Jie Li, Yexiang Liu and Jianhong Yang  (204)

41. On Formation Condition for Amorphous Phase of Ternary Fluorides by OMR method....................

................................................................... Liu Liang, Bao Xinhua, Lu Wencong, Chen Nianyi  (210)

42. Chemical Reaction and Physical Changes in the Cathode during Aluminium Electrolysis...................

..................................................................................... Lorentz Petter Lossius, Harald A. Øye  (213)

43. Some Regularities of Thermodynamic Properties of Common-Cation Molten Salt Mixtures.............

.......................... Lu Wencong, Yan Licheng, Fang Jianhui, Ding Yimin, Liu Liang, Chen Nianyi  (223)

44. Reprocessing of Ionic Melt Bath Containing High-Level Radioactive Wastes by

   Countercurrent Electromigration.....................................................................................................

................................ Haruaki Matsuura, Masahiko Matsumiya, Ryuzo Takagi and Reiko Fujita  (227)

45. Ultrasonic Velocity, Heat Capacity and Internal Pressure of the LaCl3+LiCl and LaCl3+RbCl

   Melts............................................................... V. Minchenko, V. Khokhlov and I. Korzun  (231)

46. Solubility of NiO as Cathode Material for MCFC in Alkali Carbonate Melts...................................

.................................................................... M. Mohamedi, Q. Yu, K. Kihara, Y. Hisamitsu, T. Kudo,

....................................................................... T. Itoh, M. Umeda, I. Uchida, and J. R. Selman  (235)

47. Electrodeposition of Tantalum from A Novel Low Temperature Molten Salt....................................

................... Masatsugu Morimitsu, Takamitsu Matsuo, Hiroyuki Tabata and Morio Matsunaga  (241)

48. Synthesis of Monosilane by Molten Salt Electrochemical Process....................................................

.......................................................................................... Toshiyuki Nohira and Yasuhiko Ito  (247)

49. Thermodynamic Stability of Samarium and Europium Chlorides in Molten Alkali Metal

   Chlorides............................. Alena Novoselova, Vladimir Khokhlov, and Vladimir Shishkin  (253)

50. Molecular Dynamics Simulation of Crystal Growth from MgO Melt................................................

..................................... Isao Okada, Yoshie Utsunomiya, Hiroshi Uchida, and Mamiru Aizawa  (257)

51. Electrodeposition of Compound Semiconductor Film, ZnTe, in Molten Chloride..............................

............................ Masazumi Okido, Takahiro Sakamoto, Kensuke Kuroda and Ryoichi Ichino  (263)

 

52. Stability of Materials for Molten Carbonate Fuel Cells....................................................................

................................................................... Ken-Ichiro Ota, Shigenori Mitsushima, Koichi Matsuzawa,

............................................... Yoshitaka Nishimura, Taro Yamafuku, and Nobuyuki Kamiya   (267)

53. Heat Transfer Mathematical Model for a Thermal Insulation With PCM..........................................

......................................................................................... P. M. Pavel and M. Constantinescu  (273)

54. Chemical Reactions and Cathodic Products in Fluoride Melts Containing Oxocompounds...............

...................... L. P. Polyakova, E. G. Polyakov,P. Taxil, A. V. Arakcheeva,  V. V. Grinevich  (276)

55. Approximate Calculation of Density of Alkali and Rare Earth Chlorides Molten Mixtures.................

................................................................................................................ A. Potapov, Y. Sato  (280)

56. A New Au-Na Alloy Reference Electrode in a LiF-NaF-KF Eutectic Melt.....................................

....................................................................... Huan Qiao, Toshiyuki Nohira and Yasuhiko Ito  (284)

57. DeNOx and DeSOx Catalysts-Structure, Properties and Deactivation, Formation of

Crystalline Compounds from Molten Salts during Catalysis................. …………S. B. Rasmussen,

………..R. Mattsson, K. M. Eriksen, K. Nielsen, J. Winnick, S. Boghosian, R. Fehrmann  (288)

58. Chlorination of Uranium and Rare-Earth Oxides by Use of ZrCl4 in Molten LiCl-KCl......................

................................................... Yoshiharu Sakamura, Tadashi Inoue and Hirotake Moriyama  (292)

59. Viscosity and Its Temperature Dependence of Molten Semiconductors...........................................

...................................................................................... Yuzuru Sato and Tsutomu Yamamura  (296)

60. Thermodynamic Modelling of NaF-AlF3- LiF Electrolytes..............................................................

.............................................................. Michael Somerville, Ling Zhang and Sharif Jahanshahi  (300)

61. A Performance Analysis of Molten Carbonate Fuel Cell (MCFC) Stack.........................................

....................................................................................... Sui Sheng, Zhu Xinjian, Cao Guangyi  (304)

62. Oxygen Transport in Iron Oxide-Containing Melts and the Role of Electronic Conduction...............

......................................................................................................... S. Sun and S. Jahanshahi  (308)

63. Optimization and Calculation of the CeCl3-MCl (M=Li, Na, K, Rb, Cs) Phase Diagrams................

........................................................................................ Yimin Sun, Zhiyu Qiao, Yang Zhang  (314)

64. Purification of Magnesium Using Molten Salt................................................... Toshihide Takenaka,

........................................................ Tomoyuki Fujita, Ryuta Uchida and Masahiro Kawakami  (318)

65. Evaluation of Interfacial Tension Between Liquid Steel and Molten Slag..........................................

........................................................................................ Toshihiro Tanaka* and Shigeta Hara  (322)

66. Electrochemical Fluorination of Room Temperature Molten Salt......................................................

................................................... Akimasa Tasaka, Yoshio Shodai, Junpei Yamashita, Taro Kinumoto, 

.......................... Akihiro Miyasaka, Kunitaka Momota, Kazuyasu Ibuki, and Masakatsu Ueno  (328)

67. Recovery of Uranium by Electro Deposition in Molten Salts Media.................................................

.................................................................... Pierre Taxil, Pierre Chamelot and Karine Serrano  (334)

68. Electrical Conductivity of Molten TbCl3-Tb Mixtures......................................................................

....................................................... O. Tkatcheva, A. Red’Kin, V. Shishkin, and V. Khokhlov  (340)

69. Interaction of Metal with the Salt Melt: On the Theory and Electrochemical Engineering...................

.................................................................................................................... Sergei V. Volkov  (343)

70. An in Situ Spectroscopy Study of Reactions of Some Elements Comprising Spent Nuclear

   Fuel in Molten Chlorides................................................................................................................

............................................... Vladimir A. Volkovich, Trevor R. Griffiths and Robert C. Thied  (350)

71. A Cerium Oxide Film Prepared from Molten Nitrates.....................................................................

.................................................... Wang Xindong, Liu Guangming, Liu Yanfang, Duan Shuzhen  (354)

72. The Polarization Effects on the Structures of the MCl2 Melts---Molecular Dynamics

   Simulation Study............................................................................................................................

................................. Wu Yongquan, Huang Shiping, You Jinglin, Jiang Guochang, Xu Kuangdi  (359)

73. Physical and Electrochemical Surface Characteristics of Terbium Oxide Electrode in

   Chloride Smelts at 700.............................................................. Xie Zhong, Liu Yexiang  (366)

74. Phase Diagram Determination of the Dyspromium and Potasium Chloride Melts..............................

.............................................................. Xianran Xing, Shuyu Dai, Zhenqi Zhu and Zhiyu Qiao  (371)

75. Effects of Sound Wave on Electrolysis in Cryolite-Alumina Melts and Sodium Chloride

   Solution....................................................... Jilai Xue, Harald Haarstad and Harald A. Øye  (375)

76. Surface Tension of the Molten NaCl-KCl-PbCl2 System................................................................

....................... Yan Lijun, Qiao Zhiyu, Lu Kunquan, Chen Xiumei, Jiang Guochang, You Jinglin  (379)

77. Electrochemistry of Deposition of Rare Earth Metals and Their Alloys in Molten Salts.....................

.............................................................................................................................. Yang Qiqin  (383)

78. Computer Prediction of Eutectic of Alkaline Halide Molten Salt Solution.........................................

..................................................................................... Yao Lixiu, Ye Chenzhou, Chen Nianyi  (391)

79. High Temperature Raman Spectra and Microstructure Study of Barium Metaborate Crystal

   and Its Melt...................................................................................................................................

.................... You Jinglin, Jiang Guochang, Hou Huaiyu, Wu Yongquan, Chen Hui, Xu Kuangdi  (394)

80. Development of Structurally Related Viscosity Model for Silicate Melts...........................................

............................................................................................. Ling Zhang and Sharif Jahanshahi  (398)

81. A Novel Anode Material for Molten Carbonate Fuel Cell...............................................................

........................................................................................... Minshou Zhao and Changying Sun  (402)

82. Effect of Fluoride Addition on the Electrolysis of DyCl3, NdCl3 and SmCl3 in Molten

   Chloride Bath......................... Zheng Zongyu, Suzuki T.,Tanaka R., Sato Y., Yamamura T.  (409)

83. Anode Reactions during Electrolytic Production of Aluminum..........................................................

.................................................................................... Hongmin Zhu and Donald R. Sadoway  (413)

84. Room-Temperature Ionic Liquids for Synthesis of Advanced Materials...........................................

................... Dai Sheng, Yuan Chingyao, Liang Chengdu, Rajendra D. Makote and Luo Huimin  (419)